Poly(Phenylene vinylene) anionic polyelectrolyte (PVBT-SO3) was found to be an efficient hole extraction layer for inverted perovskite solar cells. It can be cast from an aqueous solution and does not require thermal annealing for improved device performance. The devices show maximum solar cell efficiency of 15.9% and exhibit improved stability under ambient conditions and enhanced charge extraction. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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