Abstract

Abstract Rechargeable mild aqueous Zn/MnO 2 batteries are currently attracting great interest thanks to their appealing performance/cost ratio. Their operating principle relies on two complementary reversible electrodeposition reactions at the anode and cathode. Transposing this operating principle to transparent conductive windows remains an unexplored facet of this battery chemistry, which is proposed here to address with the development of an innovative bifunctional smart window, combining electrochromic and charge storage properties. The proof‐of‐concept of such bifunctional Zn/MnO 2 smart window is provided using a mild buffered aqueous electrolyte and different architectures. To maximize the device's performance, transparent nanostructured ITO cathodes are used to reversibly electrodeposit a high load of MnO 2 (up to 555 mA h m −2 with a CE of 99.5% over 200 cycles, allowing to retrieve an energy density as high as 860 mA h m −2 when coupled with a zinc metal frame), while flat transparent FTO anodes are used to reversibly electrodeposit an homogenous coating of zinc metal (up to ≈280 mA h m −2 with a CE > 95% over 50 cycles). The implementation of these two reversible electrodeposition processes in a single smart window has been successfully achieved, leading for the first time to a dual‐tinting energy storage smart window with an optimized face‐to‐face architecture.