Highly proton-conducting lanthanide metal-organic frameworks featuring highly oxygenated ligands with slow magnetic relaxation or magnetocaloric effect

Abstract

Two isoreticular lanthanide metal-organic frameworks (Ln-MOFs), {[Ln2(H2O)6(H2dobdc)6·12H2O}n (Ln = Tb3+ and Gd3+); H4dobdc = 2,5-di hydroxy-benzene-1,4-di-carboxylic acid), constructed by a hydroxy-functionalized dicarboxybenzene was synthesized and structurally characterized. Single-crystal X-ray crystallography...