Solidification structure and segregation behavior of S31254 superaustenitic stainless steel ingot containing 0 wt% B and 0.005 wt% B are investigated. The results show that serious element segregation and massive eutectics are present in the center of the ingot. By contrast, the addition of boron reduces the secondary dendrite spacing, the degree of elemental segregation, and the σ phase. Further, the effect of boron on the solidification process is studied by using the high‐temperature confocal laser scanning microscope and combined with Thermo‐Calc thermodynamic simulation results. The results show that boron can widen the solidification temperature range and greatly retard the matrix solidification. The role of boron in refining dendrite structure and inhibiting precipitation is further confirmed. The effect of boron on the constitutive equation of S31254 superaustenitic stainless steel has also been researched through isothermal compression testing in the temperature range of 950–1200 °C and strain rate range of 0.01–10 s −1 . The activation energy of the boron‐free and boron‐containing S31254 superaustenitic stainless steels based on the constitutive equation are 427.77 and 495.80 kJ mol −1 , respectively. Processing maps indicate that the instability domain is significantly reduced and the hot ductility is improved after the addition of B.

Effect of Boron on the Solidification Characteristics and Constitutive Equation of S31254 Superaustenitic Stainless Steel