Abstract

The fabrication of senary carbide (HfNbTaTiZrW)C was achieved by carbothermal reduction process combined with three different kinds of sintering paths, including conventional single-step sintering (CS) and two kinds of two-step sintering (TSS-1 and TSS-2). It is revealed that the synthesized nanosized powders (~102 nm) through carbothermal reduction exhibited excellent sintering capability to obtain a high density single-phase solid solution with homogeneous metal cation distributions at macro- and sub-micrometer scales, while atomic-level heterogeneity existed with Zr segregation. Compared to CS samples with bimodal microstructure, the application of two-step sintering significantly reduced the amounts of intergranular pores and (ZrHf)O2, accompanied with grain refinement. In particular, a well-designed TSS-2 route comprising short-term high-temperature followed by low-temperature sintering achieved ultrafine-grained bulk with grain size of 1.44±0.22 μm and excellent mechanical properties of elastic modulus of 480 MPa, microhardness of 23.4 GPa, and fracture toughness of 3.8 MPa·m1/2.