Abstract

A Fe(OTf)3 and γ-cyclodextrin catalyzed hydroarylation of alkenes with 1-naphthols and 2-naphthols is demonstrated. This efficient and general method could deliver a wide range of benzyl-naphthols from readily available starting materials with high chemo- and regioselectivity in up to 99% yield with no need for a strong base or additive.