Abstract

Sorption-based atmospheric water harvesting (SAWH) with metal–organic frameworks (MOFs) offer a promising solution to freshwater scarcity in arid regions. However, given the powder nature of MOFs, scaling-up such a concept with industrially favorable monolithic MOFs in bulky sizes remains challenging. In this study, a pore vertically aligned nanocomposite sorbent where MOF-801 is anchored at the polymeric structure surface was prepared via Fe3+-induced crosslinking and directional freezing methods. The continuous vertically aligned hierarchical pores not only offer sufficient sites for MOF-801 loading but also provide rapid moisture transport channels, as well as high solar-thermal conversion efficiency, resulting in a rapid ab/desorption duration of 2 h (including an absorption process for 1 h and a desorption process for 1 h under 1 sun irradiation) and multicycle daily water production of 1.40 L kg−1 at low RH of 20 % and 5.57 L kg−1 at higher RH of 80 %, respectively, which is outperformed most of the state-of-the-art MOFs based SAWH materials. This work provides a simple and effective way to shorten MOF-801 ab/desorption duration, which has great means for designing of high-performance solar-driven water harvesting materials.