Enantioselective Synthesis of Unsymmetrical α,α-Diarylacetates via Organocatalyzed Formal C-H Insertion Reactions of Sulfoxonium Ylides with Indoles and Pyrroles
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Authors
Xin Yue
Xin Yue•Shi-Jia Li•Wengang Guo
Published
January 1, 2024
Abstract
A chiral phosphoric acid-catalyzed highly enantioselective formal C–H insertion reaction of N–H free indole and pyrrole with sulfoxonium ylides has been developed (up to 95% yield and 97% ee).
