Abstract

A planar fused-ring electron acceptor (IC-C6IDT-IC) based on indacenodithiophene is designed and synthesized. IC-C6IDT-IC shows strong absorption in 500–800 nm with extinction coefficient of up to 2.4 × 105 M–1 cm–1 and high electron mobility of 1.1 × 10–3 cm2 V–1 s–1. The as-cast polymer solar cells based on IC-C6IDT-IC without additional treatments exhibit power conversion efficiencies of up to 8.71%.