Advanced MaterialsVolume 24, Issue 42 p. 5703-5707 Communication Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2 Capturing Materials Yali Luo, Yali Luo Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorBuyi Li, Buyi Li Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorWei Wang, Wei Wang State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P.R. ChinaSearch for more papers by this authorKangbing Wu, Kangbing Wu Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorBien Tan, Corresponding Author Bien Tan bien.tan@mail.hust.edu.cn. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaHubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.Search for more papers by this author Yali Luo, Yali Luo Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorBuyi Li, Buyi Li Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorWei Wang, Wei Wang State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P.R. ChinaSearch for more papers by this authorKangbing Wu, Kangbing Wu Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaSearch for more papers by this authorBien Tan, Corresponding Author Bien Tan bien.tan@mail.hust.edu.cn. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. ChinaHubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.Search for more papers by this author First published: 25 September 2012 https://doi.org/10.1002/adma.201202447Citations: 386Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Aromatic heterocyclic microporous polymers with high surface areas are obtained by directly crosslinking of the heterocyclic monomers under mild conditions. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit high CO2 adsorption capacity and selectivity. At 273 K, the CO2/N2 selectivity of Py-1 is about 117, which is among the highest the reported microporous materials. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_201202447_sm_suppl.pdf4.3 MB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume24, Issue42November 8, 2012Pages 5703-5707 RelatedInformation