Using ${t}_{2g}$ Wannier functions, a low-energy Hamiltonian is derived for orthorhombic $3{d}^{1}$ transition-metal oxides. Electronic correlations are treated with a new implementation of dynamical mean-field theory for noncubic systems. Good agreement with photoemission data is obtained. The interplay of correlation effects and cation covalency (${\mathrm{GdFeO}}_{3}$-type distortions) is found to suppress orbital fluctuations in ${\mathrm{LaTiO}}_{3}$ and even more in ${\mathrm{YTiO}}_{3}$, and to favor the transition to the insulating state.

Mott Transition and Suppression of Orbital Fluctuations in Orthorhombic<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mn>3</mml:mn><mml:msup><mml:mi>d</mml:mi><mml:mn>1</mml:mn></mml:msup></mml:math>Perovskites

Mott Transition and Suppression of Orbital Fluctuations in Orthorhombic3d1Perovskites