Abstract Phase Change Materials (PCMs) stand out as a promising solution within the current array of Thermal Energy Storage (TES) technologies, thanks to their superior energy storage capacities (compared to sensible solutions) and technological readiness. Nonetheless, the limited thermal conductivity of these materials may lead to incomplete phase transitions during use, resulting in a decrease in their effective energy storage capabilities. The major solutions to mitigate this issue that are present in literature either require a significant modification in the heat exchanger design (e.g. by fins) or are costly and still lack robustness and reliability (e.g. by additivities). In this study, the use of copper wools is proposed as fillers within a PCM-based heat exchanger prototype, and the assessment of its impact on the heat transfer behaviour of the material is evaluated by performing charging and discharging processes. This type of inclusion was chosen as it is relatively cheap, it can be implemented within an already existing heat exchanger, and it does not suffer from segregation. Two different wools were tested in two configurations, thus resulting in five test cases (four containing the wools and one containing solely PCM). The promising results, especially the remarkable decrease in the time needed for the complete solidification of the PCM within the tank (up to 67%), open the opportunity to additional numerical analyses regarding different configurations and/or materials, thus possibly targeting further optimizations in terms of the specific energy density and the specific power density.

Assessing the impact of copper wools on a phase change material-based TES tank prototype