Self-Assembled Triple-Conducting Nanocomposite as a Superior Protonic Ceramic Fuel Cell Cathode

Abstract

Here, we report an oxygen ion-proton-electron-conducting nanocomposite, BaCo0.7(Ce0.8Y0.2)0.3O3-δ (BCCY), derived from a self-assembly process, as a high-performance protonic ceramic fuel cell (PCFC) or mixed O2−/H+ dual-ion conducting fuel cell (dual-ion FC) cathode. Self-assembly during high-temperature calcinations results in the formation of a nanocomposite consisting of a mixed H+/e− conducting BaCexYyCozO3-δ (P-BCCY) phase and mixed O2−/e− conducting BaCoxCeyYzO3-δ (M-BCCY) and BaCoO3-δ (BC) phases. The interplay between these phases promotes the oxygen reduction reaction (ORR) kinetics of this composite cathode and improves its thermo-mechanical compatibility by tempering the mismatch in thermal expansion coefficient (TEC). When tested as the cathode in anode-supported dual-ion FCs and PCFCs, peak power densities (PPDs) of 985 and 464 mW cm−2, respectively, are achieved at 650°C while maintaining a robust operational stability of 812 h at 550°C. This material is ideally suited for high-performance cathodes for PCFCs and dual-ion FCs, greatly accelerating the commercialization of this technology.