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Scanning Tunneling Microscopy Observations of Benzene Molecules on the Rh(111)-(3 × 3) (C6H6</...

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Jun 6, 1988
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Abstract

Scanning tunneling microscopy (STM) images of the (3 \ifmmode\times\else\texttimes\fi{} 3) superlattice of benzene and carbon monoxide coadsorbed on the Rh(111) surface reveal a well-ordered array of ringlike features associated with individual benzene molecules, while CO is not resolved. Images further show translational domain boundaries, step-edge structures, and evidence for surface diffusion. The origin of the STM image contrast of these molecules and implications for STM imaging of other molecular adsorbates are briefly discussed.

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