ResearchHub Logo
Currency
Display format
RSCUSD

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation

Authors
Taichiro TougeYoshihito KayakiTakao Ikariya
Journal
Journal of the American Chemical Society
Published
August 26, 2011

Abstract

Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high levels of enantioselectivity.

Supporters

Support the authors with ResearchCoin

Topics

DOI

10.1021/ja207283t

License

Unknown License
Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Cata... | ResearchHub