Abstract In this work, unique porous carbon sheets (PCSs) are developed via a facile synthesis. The obtained PCS delivers long‐range conductive framework, abundant active interfaces, rich element doping, and notably a high inner porosity that builds up an admirable 3D network for multidirectional ion transfer. Such unique architecture and surface chemistry enable ultrafast sulfur electrochemistry as well as high‐efficiency inhibition on polysulfide shuttling via the dually physical and chemical sulfur confinement. The PCS‐based sulfur electrodes achieve superb rate capability up to 10 C, outstanding cyclability over 1000 cycles, and high areal capacity of 4.8 mA h cm −2 . This work offers an appealing model of material engineering for fast and reliable lithium–sulfur batteries, as well as guidance for rational structural design in extended energy storage and conversion systems.

3D Porous Carbon Sheets with Multidirectional Ion Pathways for Fast and Durable Lithium–Sulfur Batteries