A 3D current collector made of covalently connected carbon nanostructures is presented, which can significantly improve battery performance when used as the cathode and/or anode. A Li–S cell assembled using these current collectors, with the cathode loaded with elemental sulfur and the anode loaded with lithium metal, delivers a high-rate capacity of 860 mA h g−1 at 12 C. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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