In recent times, the global population explosion and growing depletion of fossil fuels have compelled academics and scientists to do extensive research on alternate energy sources and energy storage techniques. A hydrothermal approach was used to create Copper (II) oxide (Cu2O), Manganese oxide (MnO2), Nickel oxide (NiO), and Copper@Manganese@Nickel (Cu2O@MnO2@NiO) oxide composite electrodes. Sarcophrynium Brachystachys leaves extract was used equally as a bolstering mediator. According to the Debye-Scherer equation, the crystallites size of different nanoparticles (NPs) were established to be 29.45, 24.22, 26.33 and 20.24 nm for Cu2O, MnO2, NiO, and Cu2O@MnO2@NiO, respectively, based on X-ray diffraction (XRD) experiments. According to electrochemical examinations, assessed specific capacitances for Cu2O, MnO2, NiO, and Cu2O@MnO2@NiO obtained by cyclic voltammetry (CV) using 1.00 mV/s scan rates are 785, 955, 825 and 1092 F/g, respectively. The obtained results clearly showed that separate metallic oxides specific capacitances compared with composites specific capacitance using Sarcophrynium Brachystachys leaves extract, a biological and natural constituent stands superior. Sarcophrynium Brachystachys leaves extract enhanced the synergistic impact between constituents' ions via lowering electrode resistances, raising electrode conductivity and improving electrode characteristics.