Solar powered interfacial water evaporation has become one of the most direct and sustainable technologies for seawater desalination. However, developing an efficient, stable evaporator with good salt resistance is a critical and challenging. In this work, MoS2-CNT@C membranes synthesized by loading 1T/2H MoS2 flower spheres on the CNT@C hierarchically porous membrane by hydrothermal method are used as solar water evaporators. MoS2-CNT@C membranes, as photothermal conversion materials, have broadband solar absorption capacity and good hydrophilicity. The porous structure of CNT@C membrane can provide great water transport channels, and the decoration of flower spheres MoS2 enhances the internal reflection which can increase the sunlight absorption capacity, resulting in a jump in water evaporation properties. The membrane has a high evaporation rate of 2.53 kg m−2h−1 under one sun illumination. In addition, the evaporation rate of the sample in seawater reaches 2.51 kg m−2h−1, similar to that in the pure water, and remains stable after several evaporation cycles, ensuring that high quality fresh water can be produced during the desalination.