Abstract Droplet‐based electricity generators (DEGs) are increasingly recognized for their potential in converting renewable energy sources. This study explores the interplay of surface hydrophobicity and stickiness in improving DEG efficiency. It find that the high‐performance C‐WaxDEGs leverage both these properties. Specifically, DEGs incorporating polydimethylsiloxane (PDMS) with carnauba wax (C‐wax) exhibit increased output as surface stickiness decreases. Through experimental comparisons, PDMS with 1wt.% C‐wax demonstrated a significant power output increase from 0.07 to 1.2 W m − 2 , which attribute to the minimized adhesion between water molecules and the polymer surface, achieved by embedding C‐wax into PDMS surface to form microstructures. This improvement in DEG performance is notable even among samples with similar surface potentials and contact angles, suggesting that C‐wax's primary contribution is in reducing surface stickiness rather than altering other surface properties. The further investigations into the C‐WaxDEG variant with 1wt.% C‐wax PDMS uncover its potential as a sensor for water quality parameters such as temperature, pH, and heavy metal ion concentration. These findings open avenues for the integration of C‐WaxDEGs into flexible electronic devices aimed at environmental monitoring.
