We study signatures of R-parity violation in the production of supersymmetricparticles at the LHC, and the subsequent decay of the lightest neutralino beingthe end product of a supersymmetric cascade decay. In doing so, we payparticular attention to the possible flavour structure of the operators, andhow one may discriminate between different possibilities. A neutralino LSPwould couple to all quarks and leptons and a comparative study of its decaysprovides an optimal channel for the simultaneous study of all 45 R-violatingoperators. By studying the expected signals from all these operators, wedemonstrate the ability to understand whether more than one coupling dominates,and to map the experimental signatures to operator hierarchies that can then becompared against theoretical models of flavour. Detailed comparisons withbackgrounds, including those from MSSM cascade decays are made, using thePYTHIA event simulator.