Abstract We present the projected rotational velocity and molecular abundances for HD 33632 Ab obtained via Keck Planet Imager and Characterizer (KPIC) high-resolution spectroscopy. HD 33632 Ab is a nearby benchmark brown dwarf companion at a separation of ∼20 au that straddles the L–T transition. Using a forward-modeling framework with on-axis host star spectra, which provides self-consistent substellar atmospheric and retrieval models for HD 33632 Ab, we derive a projected rotational velocity of 53 ± 3 km s −1 and carbon monoxide and water mass fractions of logCO = −2.3 ± 0.3 and logH 2 O = −2.7 ± 0.2, respectively. The inferred carbon-to-oxygen ratio (C/O = 0.58 ± 0.14), molecular abundances, and metallicity ([C/H] = 0.0 ± 0.2 dex) of HD 33632 Ab are consistent with its host star. Although detectable methane opacities are expected in L–T transition objects, we did not recover methane in our KPIC spectra, partly due to the high v sin i and to disequilibrium chemistry at the pressures to which we are sensitive. We parameterize the spin as the ratio of rotation to the breakup velocity, and compare HD 33632 Ab to a compilation of &gt;200 very low-mass objects ( M ≲ 0.1 M ⊙ ) that have spin measurements in the literature. There appears to be no clear trend for the isolated low-mass field objects versus mass, but a tentative trend is identified for low-mass companions and directly imaged exoplanets, similar to previous findings. A larger sample of close-in gas giant exoplanets and brown dwarfs will critically examine our understanding of their formation and evolution through rotation and chemical abundance measurements.

Rotation and Abundances of the Benchmark Brown Dwarf HD 33632 Ab from Keck/KPIC High-resolution Spectroscopy